苯硫酚鈉
外觀
苯硫酚鈉 | |
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識別 | |
CAS號 | 930-69-8 ![]() |
性質 | |
化學式 | C6H5NaS |
摩爾質量 | 132.16 g·mol−1 |
外觀 | 白色固體[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
苯硫酚鈉是一種硫酚鹽,化學式為C6H5SNa。它可由苯硫酚和氫氧化鈉在水或乙醇中反應製得。[1][2]
反應
[編輯]苯硫酚鈉和鹽酸反應,可以得到苯硫酚。[3]它和4-硝基重氮苯氯化物反應,可以得到(4-硝基苯基偶氮硫基)苯。[4]
參考文獻
[編輯]- ^ 1.0 1.1 Dillon M. Love; et al. Amine Induced Retardation of the Radical-Mediated Thiol–Ene Reaction via the Formation of Metastable Disulfide Radical Anions. J. Org. Chem. 2018, 83, 5, 2912–2919. doi:10.1021/acs.joc.8b00143.
- ^ Pooja Dubey; et al. Sonogashira Coupling (Cu/Amine-Free) of ArBr/Cl in Aerobic Condition and N-Benzylation of Aniline with Benzyl Alcohol Catalyzed by Complexes of Pd(II) with Sulfated/Selenated NHCs. ChemistrySelect (2020), 5(10), 2925-2934. doi:10.1002/slct.201904819.
- ^ Shuai Han; et al. Farnesyl Pyrophosphate Synthase as a Target for Drug Development: Discovery of Natural-Product-Derived Inhibitors and Their Activity in Pancreatic Cancer Cells. J. Med. Chem. 2019, 62, 23, 10867–10896. doi:10.1021/acs.jmedchem.9b01405.
- ^ Boldyrev, B. G.; Grivnak, L. M. Study of thiosulfonic acids. XXXI. (Arylazo)arenethiosulfonates. Zhurnal Organicheskoi Khimii. 1984, 20 (2): 362-369. ISSN 0514-7492.