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苯硫酚钠

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苯硫酚钠
识别
CAS号 930-69-8  checkY
性质
化学式 C6H5NaS
摩尔质量 132.16 g·mol−1
外观 白色固体[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

苯硫酚钠是一种硫酚盐,化学式为C6H5SNa。它可由苯硫酚氢氧化钠在水或乙醇中反应制得。[1][2]

反应

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苯硫酚钠和盐酸反应,可以得到苯硫酚。[3]它和4-硝基重氮苯氯化物反应,可以得到(4-硝基苯基偶氮硫基)苯。[4]

参考文献

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  1. ^ 1.0 1.1 Dillon M. Love; et al. Amine Induced Retardation of the Radical-Mediated Thiol–Ene Reaction via the Formation of Metastable Disulfide Radical Anions. J. Org. Chem. 2018, 83, 5, 2912–2919. doi:10.1021/acs.joc.8b00143.
  2. ^ Pooja Dubey; et al. Sonogashira Coupling (Cu/Amine-Free) of ArBr/Cl in Aerobic Condition and N-Benzylation of Aniline with Benzyl Alcohol Catalyzed by Complexes of Pd(II) with Sulfated/Selenated NHCs. ChemistrySelect (2020), 5(10), 2925-2934. doi:10.1002/slct.201904819.
  3. ^ Shuai Han; et al. Farnesyl Pyrophosphate Synthase as a Target for Drug Development: Discovery of Natural-Product-Derived Inhibitors and Their Activity in Pancreatic Cancer Cells. J. Med. Chem. 2019, 62, 23, 10867–10896. doi:10.1021/acs.jmedchem.9b01405.
  4. ^ Boldyrev, B. G.; Grivnak, L. M. Study of thiosulfonic acids. XXXI. (Arylazo)arenethiosulfonates. Zhurnal Organicheskoi Khimii. 1984, 20 (2): 362-369. ISSN 0514-7492.