五氯苯甲硫醚
| 五氯苯甲硫醚 | |
|---|---|
| 識別 | |
| CAS號 | 1825-19-0 
|
| 性質 | |
| 化學式 | C7H3Cl5S |
| 摩爾質量 | 296.43 g·mol−1 |
| 外觀 | 白色固體[1] |
| 熔點 | 93-94 °C[1] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
五氯苯甲硫醚是一種有機化合物，化學式為C7H3Cl5S。它可由五氯苯硫酚和氫氧化鈉反應，再與硫酸二甲酯反應製得。[1]在自然界中，它可以由生物轉化五氯硝基苯產生。[2]它可以被硝酸或在通電下被氧氣氧化為甲基五氯苯基亞碸。[3][4]
參考文獻
[編輯]- ^ 1.0 1.1 1.2 Marshall Kulka. Reactions of Hexachlorobenzene with Mercaptides. J. Org. Chem. 1959, 24, 2, 235–237. doi:10.1021/jo01084a021.
- ^ Teng, Ying; Wang, Xiaomi; Zhu, Ye; Chen, Wei; Christie, Peter; Li, Zhengao; Luo, Yongming. Biodegradation of pentachloronitrobenzene by Cupriavidus sp. YNS-85 and its potential for remediation of contaminated soils. Environmental Science and Pollution Research (2017), 24(10), 9538-9547. doi:10.1007/s11356-017-8640-2.
- ^ Sologub, L. S.; et al. Synthesis and fungicidal properties of sulfur-containing derivatives of pentachlorobenzene（俄文）. Fiziologicheski Aktivnye Veshchestva (1980), 12, 83-85. ISSN 0533-1153.
- ^ Cheng, Zhen; et al. Electrochemical Scalable Sulfoxidation of Sulfides with Molecular Oxygen and Water. European Journal of Organic Chemistry (2021), 2021(26), 3743-3747. doi:10.1002/ejoc.202100610.