五氯苯甲硫醚
| 五氯苯甲硫醚 | |
|---|---|
| 识别 | |
| CAS号 | 1825-19-0 
|
| 性质 | |
| 化学式 | C7H3Cl5S |
| 摩尔质量 | 296.43 g·mol−1 |
| 外观 | 白色固体[1] |
| 熔点 | 93-94 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
五氯苯甲硫醚是一种有机化合物，化学式为C7H3Cl5S。它可由五氯苯硫酚和氢氧化钠反应，再与硫酸二甲酯反应制得。[1]在自然界中，它可以由生物转化五氯硝基苯产生。[2]它可以被硝酸或在通电下被氧气氧化为甲基五氯苯基亚砜。[3][4]
参考文献
[编辑]- ^ 1.0 1.1 1.2 Marshall Kulka. Reactions of Hexachlorobenzene with Mercaptides. J. Org. Chem. 1959, 24, 2, 235–237. doi:10.1021/jo01084a021.
- ^ Teng, Ying; Wang, Xiaomi; Zhu, Ye; Chen, Wei; Christie, Peter; Li, Zhengao; Luo, Yongming. Biodegradation of pentachloronitrobenzene by Cupriavidus sp. YNS-85 and its potential for remediation of contaminated soils. Environmental Science and Pollution Research (2017), 24(10), 9538-9547. doi:10.1007/s11356-017-8640-2.
- ^ Sologub, L. S.; et al. Synthesis and fungicidal properties of sulfur-containing derivatives of pentachlorobenzene（俄文）. Fiziologicheski Aktivnye Veshchestva (1980), 12, 83-85. ISSN 0533-1153.
- ^ Cheng, Zhen; et al. Electrochemical Scalable Sulfoxidation of Sulfides with Molecular Oxygen and Water. European Journal of Organic Chemistry (2021), 2021(26), 3743-3747. doi:10.1002/ejoc.202100610.