二苯基硒
| 二苯基硒 | |
|---|---|
| 識別 | |
| CAS號 | 1132-39-4 
|
| PubChem | 14333 |
| ChemSpider | 13694 |
| SMILES |
|
| 性質 | |
| 化學式 | C12H10Se |
| 摩爾質量 | 233.17 g·mol−1 |
| 外觀 | 淺黃色粘稠液體 |
| 沸點 | 165–167 °C（12 mm Hg） |
| 危險性 | |
GHS危險性符號  
| |
| GHS提示詞 | 危險 |
| H-術語 | H301, H331, H373, H410 |
| P-術語 | P260, P261, P264, P270, P271, P273, P301+316, P304+340, P316, P319, P321, P330, P391, P403+233 |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
二苯基硒是一種有機化合物，化學式為C12H10Se。它可由碘苯、硒和碳酸鉀在碘化亞銅催化下於二甲基亞碸中加熱反應製得，[1]它也能由二苯基二硒和叔丁醇鉀在二甲基亞碸中反應得到。[2]它可以被過氧化氫氧化為二苯基亞硒碸[3]，或被次氯酸鈉氧化為二苯基硒碸。[4]
參考文獻
[編輯]- ^ Li, Yaming; et al. A Highly Efficient Method for the Copper-Catalyzed Selective Synthesis of Diaryl Chalcogenides from Easily Available Chalcogen Sources. European Journal of Organic Chemistry (2011), 2011(36), 7331-7338. doi:10.1002/ejoc.201101121.
- ^ Kumar, Amit; et al. Potassium tert-butoxide-mediated synthesis of unsymmetrical diaryl ethers, sulfides and selenides from aryl bromides. Tetrahedron (2013), 69(26), 5383-5392. doi:10.1016/j.tet.2013.04.113.
- ^ Loskutov, V. A.; et al. Synthesis of 9-oxoselenoxanthenium and triarylselenonium hexafluorophosphates. Russian Journal of General Chemistry (2015), 85(5), 1093-1097. doi:10.1134/S1070363215050163.
- ^ Khurana, Jitender M.; et al. Rapid Oxidation of Selenides, Selenoxides, Tellurides, and Telluroxides with Aqueous Sodium Hypochlorite. Phosphorus, Sulfur and Silicon and the Related Elements (2003), 178 (6), 1369-1375. doi:10.1080/10426500307909.