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用户:Bcnof/sandbox

维基百科，自由的百科全书

分支
经典热力学 · 统计力学 · 化学热力学 · 平衡热力学 / 非平衡热力学

定律
零 · 一 · 二 · 三

热力学系统
热力学状态: 状态方程理想气体 · 真实气体物态 · 热力学平衡 · 控制体积 · 过程: 等压过程 · 等容过程 · 等温过程 · Adiabatic · Isentropic · Isenthalpic Quasistatic · Polytropic · 自由膨胀 · 可逆过程 · 不可逆过程 · Endoreversibility · 循环: 热机 · 热泵 · 热机效率

热力学性质
Property diagrams Intensive and extensive properties · State functions:Temperature / Entropy (intro.) ? Pressure / Volume ? Chemical potential / Particle no. ?(? Conjugate variables)Vapor quality Reduced properties · Process functions:Work · Heat

Material properties

c=

$T$	$\partial S$
$N$	$\partial T$

\beta =-

$1$	$\partial V$
$V$	$\partial p$

\alpha =

$1$	$\partial V$
$V$	$\partial T$

Property database

Equations
Carnot's theorem Clausius theorem Fundamental relation Ideal gas law Maxwell relations · Table of thermodynamic equations

Free energy · Free entropy ·

Internal energy	$U(S,V)$
Enthalpy	$H(S,p)=U+pV$
Helmholtz free energy	$A(T,V)=U-TS$
Gibbs free energy	$G(T,p)=H-TS$

History and culture

Philosophy:Entropy and time · Entropy and life Brownian ratchet Maxwell's demon Heat death paradox Loschmidt's paradox Synergetics · History:General · Heat · Entropy · Gas laws Perpetual motionTheories:Caloric theory · Vis viva Theory of heat Mechanical equivalent of heat Motive powerPublications:"An Experimental Enquiry Concerning ... Heat""On the Equilibrium of Heterogeneous Substances""Reflections on theMotive Power of Fire" · Timelines of:Thermodynamics · Heat engines · Art:Maxwell's thermodynamic surface · Education:Entropy as energy dispersal

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