4-硝基苯并-15-冠-5
外观
4-硝基苯并-15-冠-5 | |
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识别 | |
CAS号 | 60835-69-0 ![]() |
SMILES |
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性质 | |
化学式 | C14H19NO7 |
摩尔质量 | 313.3 g·mol−1 |
熔点 | 95-96 °C[1] |
相关物质 | |
相关化学品 | 15-冠-5 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
4-硝基苯并-15-冠-5是一种有机化合物,化学式为C14H19NO7。它可由苯并-15-冠-5硝化制得。[2][3]在钯催化下,它可以被水合肼还原为4-氨基苯并-15-冠-5。[4]
参考文献
[编辑]- ^ Sadovskaya, N. Yu.; Glushko, V. N.; Retivov, V. M.; Belus’, S. K.; Grokhovskii, V. V. Synthesis and properties of macroheterocyclic azomethines based on 4-aminobenzo-15-crown-5. Russian Journal of General Chemistry. 2015-12, 85 (12): 2771–2777. ISSN 1070-3632. doi:10.1134/S1070363215120191 (英语).
- ^ Glushko, Valentina N.; Sadovskaya, Natalya Yu.; Kozhuhov, Vadim I.; Blokhina, Lidiya I.; Antropova, Irina A.; Petina, Ekaterina S.; Retiviov, Vasiliy М.; Melnikova, Ekaterina Yu. Production of Macrocyclic Polyether Benzo-15-Crown-5 and its Functional Derivatives. Oriental Journal of Chemistry. 2017-08-28, 33 (04): 1689-1697. doi:10.13005/ojc/330413.
- ^ Yang, Jye-Shane; Hwang, Chung-Yu; Chen, Mon-Yao. Bimodal fluorescence signaling based on control of the excited-state conformational twisting and the ground-state protonation processes. Tetrahedron Letters. 2007-04-23, 48 (17): 3097-3102. ISSN 0040-4039. doi:10.1016/j.tetlet.2007.02.120.
- ^ Bunchuay, Thanthapatra; Docker, Andrew; Eiamprasert, Utt; Surawatanawong, Panida; Brown, Asha; Beer, Paul D. Chalcogen Bond Mediated Enhancement of Cooperative Ion‐Pair Recognition. Angewandte Chemie International Edition. 2020-07-13, 59 (29): 12007-12012. ISSN 1433-7851. doi:10.1002/anie.202001125 (英语).