2-噻吩亚甲基丙二腈
| 2-噻吩亚甲基丙二腈 | |
|---|---|
malononitrile.svg)
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| 识别 | |
| CAS号 | 28162-32-5 
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| SMILES |
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| 性质 | |
| 化学式 | C8H4N2S |
| 摩尔质量 | 160.2 g·mol−1 |
| 熔点 | 89-92 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
2-噻吩亚甲基丙二腈是一种有机化合物，化学式为C8H4N2S。它可由噻吩-2-甲醛和丙二腈在水中反应制得。[2]
反应
[编辑]2-噻吩亚甲基丙二腈可以被汉奇酯还原为2-噻吩甲基丙二腈。[3]
它和亚磷酸二乙酯反应在纳米氧化锌催化下反应，可以得到P-[2,2-二氰基-1-(2-噻吩基)乙基]膦酸二乙酯。[4]
参考文献
[编辑]- ^ Shaik Sultana; et al. Nitrogen-Doped TiO2 Nanotubes-Catalyzed Synthesis of Small D-π-A-Type Knoevenagel Adducts and β-Enaminones. European Journal of Organic Chemistry. 2023. 26 (10): e202300032.
- ^ Palasz, Aleksandra. Synthesis of fused uracils: pyrano[2,3-d]pyrimidines and 1,4-bis(pyrano[2,3-d]pyrimidinyl)benzenes by domino Knoevenagel/Diels-Alder reactions. Monatshefte fuer Chemie (2012), 143 (8), 1175-1185. doi:10.1007/s00706-012-0781-x.
- ^ Yang, Yong-Qing; et al. A Convenient Heterogeneous Reduction of Knoevenagel Product by Hantzsch Ester and Its Development into Reductive Alkylation of Malononitrile. Chinese Journal of Chemistry (2014), 32 (7), 650-653. doi:10.1002/cjoc.201400144.
- ^ Hosseini-Sarvari, Mona; et al. Nanosized zinc oxide as a catalyst for the rapid and green synthesis of β-phosphono malonates. Tetrahedron (2008), 64 (23), 5519-5523. doi:10.1016/j.tet.2008.03.095.