四氮杂卟啉
| 四氮杂卟啉 | |
|---|---|
| |
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| IUPAC名 Porphyrazine | |
| 别名 | 5,10,15,20-Tetraazaporphine; Tetraazaporphine; Tetraazaporphyrin; Tetrazaporphin |
| 识别 | |
| CAS号 | 500-77-6 
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| PubChem | 5014177 |
| ChemSpider | 24785772 |
| SMILES |
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| 性质 | |
| 化学式 | C16H10N8 |
| 摩尔质量 | 314.3 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
四氮杂卟啉是一种四吡咯基大环化合物，化学式为C16H10N8，其结构与卟啉或酞菁相似。Patrick Linstead最早开始了四氮杂卟啉的研究。[1]它的一个结构拓展是四吡嗪并四氮杂卟啉。[2]
它在紫外、可见光和近红外光谱范围内的强烈电子吸收，[3]Soret带位于300 - 400 nm，Q带在>600 nm处。[4]
参考文献
[编辑]- ^ Cook, A. H.; Linstead, R. P., "Phthalocyanines. XI. The preparation of octaphenylporphyrazines from diphenylmaleinitrile." J. Chem. Soc. 1937, 929-933.DOI: 10.1039/JR9370000929
- ^ Donzello, Maria Pia; Ercolani, Claudio; Novakova, Veronika; Zimcik, Petr; Stuzhin, Pavel A. Tetrapyrazinoporphyrazines and their metal derivatives. Part I: Synthesis and basic structural information. Coordination Chemistry Reviews. 2016-02-15, 309: 107–179. ISSN 0010-8545. doi:10.1016/j.ccr.2015.09.006.
- ^ Kobayashi, N. and H. Konami (1996) Molecular orbitals and electronic spectra of phthalocyanine analogues. In Phthalocyanines: Properties and Applications, Vol. 4 (Edited by C. C. Leznoff and A. B. P. Lever), pp. 343–404. VCH Publishers, Inc., New York.
- ^ Linstead, R. P.; Whalley, M., Conjugated Macrocycles. Part XXI Tetrazaporphin and its Metallic Derivatives. J. Chem. Soc. 1952, 4839-4844.