叔戊酸叔丁酯
外观
叔戊酸叔丁酯 | |
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识别 | |
CAS号 | 16474-43-4 ![]() |
SMILES |
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性质 | |
化学式 | C9H18O2 |
摩尔质量 | 158.24 g·mol−1 |
沸点 | 120~128 °C[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
叔戊酸叔丁酯是一种有机化合物,化学式为C9H18O2。它可由叔戊酸酐和叔丁醇在二氯二氧化钼催化下反应制得。[2]它和硝酸或硫酸在二氯甲烷中反应,可以得到叔戊酸。[3][4]
参考文献
[编辑]- ^ Haynes, RK; Holden, M (1982). Formation of iodides and esters from alcohols and tributyldiiodophosphorane and diiodotriphenylphosphorane. Australian Journal of Chemistry, 35 (3), 517.doi:10.1071/CH9820517
- ^ Chien-Tien Chen; et al. Nucleophilic Acyl Substitutions of Anhydrides with Protic Nucleophiles Catalyzed by Amphoteric, Oxomolybdenum Species. J. Org. Chem. 2005, 70, 4, 1188–1197. doi:10.1021/jo048363v.
- ^ Paolo Strazzolini; et al. Nitrolysis of carboxylic t-butyl and 1-adamantyl esters. Tetrahedron Letters, 1998. 39 (50): 9255. doi:10.1016/S0040-4039(98)02079-6.
- ^ Paolo Strazzolini; et al. Efficient cleavage of carboxylic tert-butyl and 1-adamantyl esters, and N-Boc-amines using H2SO4 in CH2Cl2. Tetrahedron Letters, 2005. 46 (12): 2075. doi:10.1016/j.tetlet.2005.01.129.