亚糠基丙二腈
外观
亚糠基丙二腈 | |
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识别 | |
CAS号 | 3237-22-7 ![]() |
SMILES |
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性质 | |
化学式 | C8H4N2O |
摩尔质量 | 144.13 g·mol−1 |
外观 | 浅黄色固体[1] |
熔点 | 67—68 °C(340—341 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
亚糠基丙二腈,别名(2-呋喃亚甲基)丙二腈,是一种有机化合物,化学式为C8H4N2O。它可由糠醛和丙二腈加热反应,[2]或于水中反应制得。[3]它在甲醇中可以被汉奇酯还原为糠基丙二腈。[4]
参考文献
[编辑]- ^ 1.0 1.1 Yadav, Jhillu S.; Reddy, Basi V. Subba; Basak, Ashok K.; Visali, Boddapati; Narsaiah, Akkirala Venkat; Nagaiah, Kommu. Phosphane-catalyzed Knoevenagel condensation: A facile synthesis of α-cyanoacrylates and α-cyanoacrylonitriles. European Journal of Organic Chemistry, 2004. 3: 546-551. doi:10.1002/ejoc.200300513.
- ^ Weifan Wang; et al. Catalyst-free and Solvent-free Cyanosilylation and Knoevenagel Condensation of Aldehydes. ACS Sustainable Chem. Eng. 2019, 7, 1, 1718–1722. doi:10.1021/acssuschemeng.8b05486.
- ^ Kolagkis, Periklis X.; et al. Deciphering the Knoevenagel condensation: towards a catalyst-free and water-mediated process. Organic & Biomolecular Chemistry (2024), 22 (41), 8293-8299. doi:10.1039/D4OB01420K.
- ^ Yang, Yong-Qing; et al. A Convenient Heterogeneous Reduction of Knoevenagel Product by Hantzsch Ester and Its Development into Reductive Alkylation of Malononitrile. Chinese Journal of Chemistry (2014), 32 (7), 650-653. doi:10.1002/cjoc.201400144.