五氟苯甲醛

五氟苯甲醛
识别
CAS号	653-37-2
PubChem	69558
ChemSpider	21106527
SMILES	O=CC=1C(F)=C(F)C(F)=C(F)C1F;
性质
化学式	C7HF5O
摩尔质量	196.07 g·mol−1
外观	无色液体
密度	1.751 g/mL
熔点	20 °C
沸点	168~170 °C
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

五氟苯甲醛是一种有机化合物，化学式为C₆F₅CHO。它可由五氟苯甲醇的催化氧化制得。^[2]^[3]它可以被进一步氧化为五氟苯甲酸。^[4]它和苯甲硫醇在三乙胺存在下于乙腈中反应，可以得到4-苯甲硫基四氟苯甲醛。^[5]

参考文献

^ ^1.0 ^1.1 ^1.2 Pažitný, Andrej; Solčán, Tomáš; Végh, Daniel. Pentafluorobenzaldehyde and its utilizing in organic synthesis. Journal of Fluorine Chemistry. 2009-03-01, 130 (3) [2025-02-13]. ISSN 0022-1139. doi:10.1016/j.jfluchem.2008.12.013. （原始内容存档于2022-03-20）.
^ Adil, Syed Farooq; Assal, Mohamed E.; Shaik, Mohammed Rafi; Kuniyil, Mufsir; Hashmi, Azhar; Khan, Mujeeb; Khan, Aslam; Tahir, Muhammad Nawaz; Al‐Warthan, Abdulrahman; Siddiqui, Mohammed Rafiq H. Efficient aerial oxidation of different types of alcohols using ZnO nanoparticle–MnCO₃ ‐graphene oxide composites. Applied Organometallic Chemistry. 2020-08, 34 (8) [2025-02-13]. ISSN 0268-2605. doi:10.1002/aoc.5718. （原始内容存档于2023-11-15）（英语）.
^ Assal, Mohamed E.; Kuniyil, Mufsir; Shaik, Mohammed Rafi; Khan, Mujeeb; Al-Warthan, Abdulrahman; Siddiqui, Mohammed Rafiq H.; Adil, Syed Farooq. Synthesis, Characterization, and Relative Study on the Catalytic Activity of Zinc Oxide Nanoparticles Doped MnCO₃ , –MnO₂ , and –Mn₂O₃ Nanocomposites for Aerial Oxidation of Alcohols. Journal of Chemistry. 2017, 2017 [2025-02-13]. ISSN 2090-9063. doi:10.1155/2017/2937108. （原始内容存档于2020-02-15）（英语）.
^ Shi, Hongwei; Li, Jun; Wang, Tao; Rudolph, Matthias; Hashmi, A. Stephen K. Catalyst- and additive-free sunlight-induced autoxidation of aldehydes to carboxylic acids. Green Chemistry. 2022, 24 (15). ISSN 1463-9262. doi:10.1039/D2GC01429G （英语）.
^ Liao, Hsuan-Hung; Lee, Shao-Chi; Kao, Hsin; Hsu, Yu-Ling; Hsu, Che-Ming; Tsao, Yong-Ting; Miñoza, Shinje; Li, Li-Yun; Tsai, Zong-Nan; Chang, Kuei-Chen; Cheng, Cheng-Ku. Synthesis of perfluoroaryl sulfides at electron-poor arenes via an S_NAr step with an unexpected mechanism. Cell Reports Physical Science. 2022-08-17, 3 (8) [2025-02-13]. ISSN 2666-3864. doi:10.1016/j.xcrp.2022.101010. （原始内容存档于2023-01-23）（英语）.

[JF-1] 1.0 ^1.1 ^1.2 Pažitný, Andrej; Solčán, Tomáš; Végh, Daniel. Pentafluorobenzaldehyde and its utilizing in organic synthesis. Journal of Fluorine Chemistry. 2009-03-01, 130 (3) [2025-02-13]. ISSN 0022-1139. doi:10.1016/j.jfluchem.2008.12.013. （原始内容存档于2022-03-20）.

[2] Adil, Syed Farooq; Assal, Mohamed E.; Shaik, Mohammed Rafi; Kuniyil, Mufsir; Hashmi, Azhar; Khan, Mujeeb; Khan, Aslam; Tahir, Muhammad Nawaz; Al‐Warthan, Abdulrahman; Siddiqui, Mohammed Rafiq H. Efficient aerial oxidation of different types of alcohols using ZnO nanoparticle–MnCO₃ ‐graphene oxide composites. Applied Organometallic Chemistry. 2020-08, 34 (8) [2025-02-13]. ISSN 0268-2605. doi:10.1002/aoc.5718. （原始内容存档于2023-11-15）（英语）.

[3] Assal, Mohamed E.; Kuniyil, Mufsir; Shaik, Mohammed Rafi; Khan, Mujeeb; Al-Warthan, Abdulrahman; Siddiqui, Mohammed Rafiq H.; Adil, Syed Farooq. Synthesis, Characterization, and Relative Study on the Catalytic Activity of Zinc Oxide Nanoparticles Doped MnCO₃ , –MnO₂ , and –Mn₂O₃ Nanocomposites for Aerial Oxidation of Alcohols. Journal of Chemistry. 2017, 2017 [2025-02-13]. ISSN 2090-9063. doi:10.1155/2017/2937108. （原始内容存档于2020-02-15）（英语）.

[4] Shi, Hongwei; Li, Jun; Wang, Tao; Rudolph, Matthias; Hashmi, A. Stephen K. Catalyst- and additive-free sunlight-induced autoxidation of aldehydes to carboxylic acids. Green Chemistry. 2022, 24 (15). ISSN 1463-9262. doi:10.1039/D2GC01429G （英语）.

[5] Liao, Hsuan-Hung; Lee, Shao-Chi; Kao, Hsin; Hsu, Yu-Ling; Hsu, Che-Ming; Tsao, Yong-Ting; Miñoza, Shinje; Li, Li-Yun; Tsai, Zong-Nan; Chang, Kuei-Chen; Cheng, Cheng-Ku. Synthesis of perfluoroaryl sulfides at electron-poor arenes via an S_NAr step with an unexpected mechanism. Cell Reports Physical Science. 2022-08-17, 3 (8) [2025-02-13]. ISSN 2666-3864. doi:10.1016/j.xcrp.2022.101010. （原始内容存档于2023-01-23）（英语）.

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