三羰基环戊二烯基(五羰基锰基)钼

三羰基环戊二烯基(五羰基锰基)钼
识别
CAS号	12085-47-1
SMILES	O#C[Mn](C#O)(C#O)(C#O)(C#O)[Mo+]1234(C#O)(C#O)(C#O)[CH]=5[CH]4=[CH]3[CH-]2[CH]51;
性质
化学式	C13H5MnMoO8
摩尔质量	440.05 g·mol−1
外观	红色片状晶体
密度	1.94 g·cm−3
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三羰基环戊二烯基(五羰基锰基)钼是一种金属有机化合物，化学式为C₁₃H₅MnMoO₈。它可由环戊二烯基三羰基钼二聚体和十羰基二锰在一氧化碳气氛中反应制得。^[2]它和硫在氧化三甲胺存在下反应，可以得到二羰基环戊二烯基(μ-二硫)(三羰基锰基)钼；^[3]和硒在相似条件下反应可以得到μ-二硒类似物。^[4]

参考文献

^ ^1.0 ^1.1 B. P. Bir'yukov; et al. Metal–metal interaction in the π-cyclopentadienyltricarbonylmolybdenum–pentacarbonylmanganese complex, π-C5H5Mo(CO)3–Mn(CO)5. Chem. Commun. (London), 1968, 667-668. doi:10.1039/C19680000667.
^ Keith R. Pope; Mark S. Wrighton. Low-temperature photochemistry of (η⁵-C₅H₅)Mo(CO)₃Mn(CO)₅. Identification of an unexpectedly stable, coordinatively unsaturated heterodinuclear carbonyl complex. Inorg. Chem. 1987, 26, 14, 2321–2325. doi:10.1021/ic00261a031.
^ Richard D. Adams; O-Sung Kwon. The Addition of Platinum and Palladium Groups to the Disulfido Ligand in Cyclopentadienyl Molybdenum-Manganese Carbonyl Complexes. Journal of Cluster Science, 2003. 14, 367–379. doi:10.1023/B:JOCL.0000005069.59971.39.
^ Richard D. Adams; O-Sung Kwon. Syntheses and Reactivity of the Diselenido Molybdenum−Manganese Complex CpMoMn(CO)5(μ-Se2). Inorg. Chem. 2003, 42, 20, 6175–6182. doi:10.1021/ic030077z.

[chem-1] 1.0 ^1.1 B. P. Bir'yukov; et al. Metal–metal interaction in the π-cyclopentadienyltricarbonylmolybdenum–pentacarbonylmanganese complex, π-C5H5Mo(CO)3–Mn(CO)5. Chem. Commun. (London), 1968, 667-668. doi:10.1039/C19680000667.

[2] Keith R. Pope; Mark S. Wrighton. Low-temperature photochemistry of (η⁵-C₅H₅)Mo(CO)₃Mn(CO)₅. Identification of an unexpectedly stable, coordinatively unsaturated heterodinuclear carbonyl complex. Inorg. Chem. 1987, 26, 14, 2321–2325. doi:10.1021/ic00261a031.

[3] Richard D. Adams; O-Sung Kwon. The Addition of Platinum and Palladium Groups to the Disulfido Ligand in Cyclopentadienyl Molybdenum-Manganese Carbonyl Complexes. Journal of Cluster Science, 2003. 14, 367–379. doi:10.1023/B:JOCL.0000005069.59971.39.

[4] Richard D. Adams; O-Sung Kwon. Syntheses and Reactivity of the Diselenido Molybdenum−Manganese Complex CpMoMn(CO)5(μ-Se2). Inorg. Chem. 2003, 42, 20, 6175–6182. doi:10.1021/ic030077z.

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